Search results for "IONIC-STRENGTH DEPENDENCE"
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Quantum correlations in generalized spin star system
2006
The problem of detecting quantum signatures in the correlations formed in dynamical evolution of quantum bipartite systems receives a lot of attention in current literature. Generally speaking, the occurrence of correlations between two observables of a system does not necessarily reflect nonclassical behaviour. In this paper, the exact dynamics of a pair of uncoupled spins 1/2 interacting with a common spin 1/2 bath is investigated. Starting from a separable initial condition, the ability of the system to develop purely quantum correlations is brought to light. Physical interpretation of the concurrence function as well as a suggestion on how to measure it are given.
Hydrolysis of Monomethyl-, Dimethyl-, and Trimethyltin(IV) Cations in Fairly Concentrated Aqueous Solutions at I = 1 mol L-1 (NaNO3) and T = 298.15 K…
2011
The hydrolysis of methyltin(IV) cations at fairly high concentrations was investigated to evaluate the formation of polynuclear species in aqueous solution. The hydrolysis of monomethyltin(IV), dimethyltin(IV), and trimethyltin(IV) was studied by potentiometry at T = 298.15 K and at I = 1 mol L-1 in NaNO3 aqueous solutions. The results obtained gave evidence for the formation of the following polynuclear species, in addition to the mononuclear species already reported, which were also considered in the models proposed for the three systems investigated: [(CH3)Sn(OH)3]0, [(CH3)Sn(OH)4]-, [((CH3)Sn)2(OH)4]2+, [((CH3)Sn)2(OH)5]+, [((CH3)Sn)2(OH)7]-, [((CH3)Sn)3(OH)5]4+, [((CH3)Sn)3(OH)7]2þ, [(…